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Journal of the Chilean Chemical Society

versão On-line ISSN 0717-9707

Resumo

ATRIA, ANA MARÍA; GARLAND, MARIA TERESA  e  BAGGIO, RICARDO. CRYSTAL STRUCTURE OF HEMIKIS(TETRAKIS(μ2-2-BUTENOATO)-BIS(2-BUTENOATO)-TETRA-AQUA-DI-SAMARIUM) HEMIKIS(BIS(μ2-BUTENOATO)-TETRAKIS(2-BUTENOATO) TETRA AQUA-DI-SAMARIUM) TRIHYDRATE. J. Chil. Chem. Soc. [online]. 2014, vol.59, n.3, pp.2595-2597. ISSN 0717-9707.  http://dx.doi.org/10.4067/S0717-97072014000300014.

The structure of the title compound [Sm2(crot)6(H2O)4]2-3(H2O) (I), (crot= crotonate = butenoate = O2CCHCHCH3)] consists of two independent, centrosymmetric dimeric units, of similar composition but diverse coordination, viz., one of them doubly bridged (2×[η2:η1:μ2]) and the remaining one quadruply bridged (2×[η1:η1:μ2], 2×[η2:η1:μ2]). The asymmetric unit is completed by three solvato water molecules, one of them depleted (occupation: 0.735 (14)). The difference in bridging strengths is readily evidenced in the two quite dissimilar Sm···Sm distances observed: 4.1402 (8)Å,(doubly bridged), 3.9439 (8)Å (quadruply bridged). SmO9 polyhedra suyvey similar coordination distances which span the range 2.388 (3)-2.611 (3)Å for one of the Sm cations and 2.357 (3)-2.588 (3)Å for the other. All water hydrogens are involved in H-bonding, leading to the formation of a strongly linked 2D structure parallel to (010). These planar arrays are in turn transversally linked by one single bridging water molecule. There are in addition C= C···C=C p interactions providing both to intra as well as intra planar cohesion. The compound is isomorphous to its Gd isologue1, but the present description unveils a number of molecular and supramolecular details not discussed therein.

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