Abstract

APANDA, B et al. AMINOCARBONYLATION REACTION USING PALLADIUM COMPLEXES CONTAINING PHOSPHORUS-NITROGEN LIGANDS AS CATALYSTS. J. Chil. Chem. Soc. [online]. 2013, vol.58, n.4, pp.2136-2137. ISSN 0717-9707.  http://dx.doi.org/10.4067/S0717-97072013000400052.

The catalytic activities of palladium complexes containing phosphorus-nitrogen ligands is reported. The catalysts studied showed high activities in the aminocarbonylation of aryl iodides. The palladium complexes reported activities between 100% and 58% in the aminocarbonylation reaction. The reactions are very selective for the double carbonylative amination of aryl halides. The major product is N,N-diethyl-α-oxo benzeneacetamide (96/4). The reaction was made under mild conditions of temperature and carbon monoxide pressure.

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