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vol.52 issue3PREPARATION OF CHIRAL ORGANIC-INORGANIC SOLID HYBRIDS: USE AS SUPPORT OF CATALYSTS IN THE ENANTIOSELECTIVE HYDROGENATION OF ETHYL PYRUVATEINVESTIGATION AND OPTICAL EVALUATION OF PRECURSORS FOR THE PHOTODEPOSITION OF NANOSIZED ZnS AMORPHOUS THIN FILMS author indexsubject indexarticles search
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Journal of the Chilean Chemical Society

On-line version ISSN 0717-9707

Abstract

BARTOLINP, M et al. NITROBENZENE REDUCTION CATALIZED BY SOLUBLE CARBONYLRHODIUM COMPLEXES OF METHYL AND DIMETHYL PYRIDINE LIGANDS. J. Chil. Chem. Soc. [online]. 2007, vol.52, n.3, pp.1254-1256. ISSN 0717-9707.  http://dx.doi.org/10.4067/S0717-97072007000300014.

The catalytic reduction of nitrobenzene by rhodium(I) complexes of the type CM-[Rh(CO)2(amine)2](PF6) (amine = 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, or 2,6-dimethylpyridine) in methanol under an atmosphere of carbon monoxide is described. A single organic product, aniline, is seen in the post-reaction mixture. The amount of product formed depends upon the nature of the amine coordinated to the rhodium center

Keywords : Catalysis; nitrobenzene reduction; rhodium complexes; carbon monoxide.

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