Journal of the Chilean Chemical Society
versão On-line ISSN 0717-9707
MOYA, S. A et al. SYNTHESIS, CHARACTERIZATION AND PRELIMINARY CATALYTIC PROPERTIES OF NEW COPPER (I) COMPLEXE [Cu (pyrazolyl)2]X TYPE. J. Chil. Chem. Soc. [online]. 2010, vol.55, n.4, pp. 479-482. ISSN 0717-9707. http://dx.doi.org/10.4067/S0717-97072010000400015.
The preparation of tetracoordinated copper (I) complexes with the pyrazolyl heterocyclic nitrogen ligand is reported. The new complexes of [Cu(pyrazolyl)2] X type with X = chloride, bromine, and iodine were characterized by spectroscopic and electrochemical techniques. The results obtained show that the heterocyclic nitrogen ligand is bonded in a bidentate fashion to form monometallic complexes. Exploratory homogeneous catalysis experiments of the water-gas shift reaction (WGSR) have been accomplished by the use of copper complexes in 80 % aqueous 4-picoline solutions. For such systems, formation of H2 y CO2 was observed in the initial gas samples.
Palavras-chave : Copper Complexes; Heterocyclic Nitrogen Ligand; Pyrazolyl Ligand; WGSR.