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Journal of the Chilean Chemical Society

versión On-line ISSN 0717-9707

Resumen

PARADA, JOSÉ et al. THE STEREOSELECTIVE SYNTHESIS OF THE WERNER COMPLEX WITH SUBSTOICHIOMETRIC SUGARS. J. Chil. Chem. Soc. [online]. 2008, vol.53, n.1, pp. 1379-1381. ISSN 0717-9707.  http://dx.doi.org/10.4067/S0717-97072008000100012.

A tetranuclear complex of Co(III) with hydroxo bridges, so-called "Werner Complex", was synthesized in the presence of several sugars (1-8) with partial resolution of this complex. The sugars in 10 mol % with respect to Co(III) induce maximum resolution of the Werner complex

Palabras llave : Werner complex; hexol; sugar; Co(III); circular dichroism; dd* transition dd*; enantioselectivity.

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