Abstract

VICTORIANO, Luis I.. NEUTRAL COMPLEXES OF SILVER HALIDES AND TETRAMETHYLTHIURAM MONOSULFIDE. Bol. Soc. Chil. Quím. [online]. 2000, vol.45, n.4, pp. 583-586. ISSN 0366-1644.  http://dx.doi.org/10.4067/S0366-16442000000400009.

The preparation and characterization of 1:1 adducts of silver halides AgX (X=Cl, Br, I) with N,N,N’,N’-Tetramethylthiuram Monosulfide is reported. The products are characterized by elemental analyses, magnetic measurements and IR-Raman spectroscopy. The data are interpreted in terms of a halogen-dibridged structure of D_2h symmetry.

Keywords : Silver; Sulfur ligands; Coordination compounds.