Mid-Cenozoic SHRIMP U-Pb detrital zircon ages from metasedimentary rocks in the North Patagonian Andes of Aysén, Chile

. Previously undated low-grade metamorphic rocks from the Puerto Cisnes-Queulat area (44 ° 30’ S) contain detrital zircons of mid-Oligocene age ( ca. 28 Ma). Their outcrops represent the easternmost occurrence of the late Oligocene to early Miocene marine volcano-sedimentary Traiguén Formation; previous correlation with the Paleozoic metamorphic basement of this sector of the North Patagonian Andes is thus refuted. A similar age and provenance were obtained for a paraconglomerate bed of the La Junta Formation ca. 80 km to the north, which is thought to represent a high-energy lateral facies variation of the Traiguén Formation. Miocene plutonic rocks of the North Patagonian Batholith intruded these metasedimentary rocks, generating a contact metamorphic aureole that reaches biotite grade and overprints a previous metamorphic fabric probably formed during closure of the Traiguén Basin. Similar young ages for metamorphic rocks located immediately west of the Liquiñe-Ofqui Fault Zone 300 km north, near Ayacara, suggest a regional pattern of earliest Neogene metamorphism and rapid exhumation in this segment of the Patagonian Andes. Andes Norpatagónicos son descartadas. Una edad máxima y fuentes de procedencia similares se obtuvieron en un paraconglomerado de la Formación La Junta, unos 80 km al norte, el cual se interpreta como una variación lateral de alta energía de la Formación Traiguén. Rocas plutónicas del Mioceno pertenecientes al Batolito Norpatagónico intruyen a las rocas metasedimentarias, generan una aureola de contacto que alcanza el grado metamórfico de la biotita, y se sobrepone a una fábrica metamórfica anterior probablemente relacionada con el tectonismo producto del cierre de la cuenca Traiguén. Edades Cenozoicas similares han sido obtenidas para rocas metamórficas ubicadas inmediatamente al oeste de la Zona de Falla Liquiñe-Ofqui 300 km al norte, cerca de Ayacara, lo cual sugiere un patrón regional de metamorfismo y exhumación en una rápida sucesión durante el Neógeno más temprano en este segmento de los Andes Patagónicos.


Introduction
Evidence of the Cenozoic evolution of the North Patagonian Andes margin is partially preserved in the western slope of the Andean Cordillera ( Fig. 1). It underwent a major Neogene phase of batholith construction (Pankhurst et al., 1999) and large-scale denudation caused by transpressional tectonics (Thomson, 2002). Deformation and metamorphism were focused along the Liquiñe-Ofqui Fault Zone (LOFZ; Fig. 1), a right lateral strike-slip structure which extends for 1,000 km north of the Golfo de Penas (ca. 47° S) through the western slope of the main cordillera (Hervé, 1976(Hervé, , 1994Beck et al., 1993;Cembrano et al., 1996;Cembrano et al., 2002). The early Neogene contraction resulted in the uplift of the North Patagonian Andes and development of Miocene foreland basins.
Prior to this Neogene uplift, the Andean and extra-Andean areas of Patagonia were largely covered by marine deposits with Pacific and Atlantic affinities, respectively (e.g., Malumián and Yañez, 2011;Encinas et al., 2013;Bechis et al., 2014;Encinas et al., 2016a;Cuitiño et al., 2017), in some areas possibly with transient oceanic connection (see below). These Eocene-early Miocene marine strata ( Fig.1) represent the climax and final stage of an extensional episode that started during the early Cenozoic (Aragón et al., 2011;Hervé et al., 2017;Encinas et al., 2019), following Lower and Upper Cretaceous orogenic phases (Gianni et al., 2018 and references therein).
At ca. 40-46°S, the early mid-Cenozoic deepmarine strata cropping out in the western slope of the Andean Cordillera are spatially related to the main trace and secondary branches of the LOFZ (Figs. 1 y 2). The greatest extension is recorded in the Traiguén Formation (Espinoza and Fuenzalida, 1971), in which deep-marine turbidite deposits (Encinas et al., 2016a) are found overlying or associated with supra-subduction zone pillow lavas overprinted by ocean-floor metamorphism (Hervé et al., 1995). In some localities, the volcano-sedimentary units are profusely intruded by mafic dykes (Silva et al., 2003), resembling the emplacement of a dyke swarm on a thin and attenuated ocean-like crust.
In this work, we present SHRIMP U-Pb detrital zircon ages for intercalated packages of metapelite and metasandstone in the Puerto Cisnes-Queulat area (ca. 44°30' S), east of the main trace of the LOFZ and for a paraconglomerate sample from La Junta area. These have been previously interpreted as either Paleozoic metamorphic basement (SERNAGEOMIN, 2003) or Cenozoic clastic successions (Bobenrieth et al., 1983). The results and geological considerations presented here provide constraints on their ages of deposition and metamorphism and their tectonic significance in the context of regional mid-Cenozoic evolution of the area.

Regional tectonic and geological background
According to Cenozoic plate tectonic reconstructions based on ocean floor magnetic anomalies, the convergence between Farallon/Nazca and South America plates evolved from a low-velocity oblique subduction system during the Paleogene to a faster and nearly orthogonal subduction by late Oligocene times (e.g., Cande and Leslie, 1986;Pardo-Casas and Molnar, 1987;Somoza and Ghidella, 2005;Eagles and Scott, 2014). This change reflects the birth of the Nazca plate and rearrangement of oceanic plate boundaries in east Pacific (Lonsdale, 2005;Somoza and Ghidella, 2012).
phase partly predates the late Oligocene to early Miocene Pacific and Atlantic marine ingressions that covered wide areas of southern South America, with possible areas of transient ocean connection (e.g., Encinas et al., 2014;Bechis et al., 2014 and references therein). In the western slope of the North Patagonian Andes, deep-marine sedimentation is mostly recorded in the Ayacara (ca. 42° S) and Traiguén (ca. 44-46° S) formations (Levi et al., 1966;Espinoza and Fuenzalida, 1971; among others) ( Fig. 1). At similar latitudes on the eastern side of the Andes, coeval marine strata of the Ventana, Rio Foyel, Cerro Plataforma, La Cascada and Guadal formations have been interpreted as mainly deposited in shallower marine environments (see Encinas et al., 2018 for review).
Cordilleran-type calc-alkaline magmatism was re-established in the North Patagonian Andes by early-mid Miocene times with major pluton emplacement along the strike of the LOFZ (Pankhurst et al., 1999). This phenomenon was partly coeval with the lateral expansion of the North Patagonian Andes as evidenced by 12-18 Ma synorogenic fluvial strata in the foreland area (see Folguera et al., 2018b for review).
Intense uplift and erosion from latest Miocene times onwards are regionally recorded by apatite fission track ages (Thomson, 2002;Adriasola et al., 2005). This transpressional episode was also localised along the LOFZ and led to the exhumation of plutonic rocks of the North Patagonian Batholith.

Local geology
In the Aysén region, three main geological domains have been differentiated (Fig. 2): i) the latest Triassic Chonos accretionary prism in the Coast Range (Davidson et al., 1987;Thomson and Hervé, 2002); ii) the widespread Mesozoic-Cenozoic plutonic rocks of the North Patagonian Batholith (Pankhurst et al., 1999) together with the recent volcanic rocks of the Southern Volcanic Zone in the western slope of the main Cordillera (López-Escobar et al., 1995) and the Paleozoic Main Range Metamorphic Complex ; and iii) the Mesozoic to Cenozoic volcano-sedimentary successions (Haller and Lapido, 1980) overlying the Paleozoic Eastern Andes Metamorphic Complex in the eastern slope FIG. 2. Sketch map of the geology of Aysén region, 43°-46° S. Main faults after Thomson (2002). Modified from SERNAGEOMIN (2003). of the Andes . The boundary between the first two domains is, in some areas, marked by the LOFZ (Fig. 1).
The oldest rocks recognized in the study area are the poorly known schistose, medium-to-high grade, metamorphic rocks of the Main Range Metamorphic Complex (MRMC), whose outcrops can be found in Isla Magdalena and nearby inland areas (Fig. 2). Hervé et al. (2003) reported a mid-Paleozoic maximum sedimentation age for the sedimentary protolith of a sillimanite-bearing quartz micaschist sampled in the northern shore of Isla Magdalena. No radiometric age has yet been determined for low-grade metamorphic rocks located inland at the same latitudes, in the Cuesta Queulat area and south of Puerto Cisnes, some of which have been considered to be Paleozoic (e.g., SERNAGEOMIN, 2003).
In Aysén, early-mid Paleogene volcanic and sedimentary rocks are mainly located east of the Andean Cordillera, near the Chile-Argentina international border (Fig. 2), and have been interpreted as formed in an extensional setting (e.g., Encinas et al., 2018). In particular, alkaline basalts in the Chile Chico-Balmaceda area have been related to the development of an asthenospheric window associated with Eocene subduction of the Aluk-Farallon seismic ridge below this portion of South America (Espinoza et al., 2005). Mid-Eocene marine strata of the Puerto Good Sequence in the Golfo de Penas area also imply extension of the forearc at that time (Forsythe et al., 1985). Apatite fission-track ages of 28-30 Ma obtained by Thomson et al. (2001) in the archipelagos north of 46° S indicate little denudation in the forearc since Rupelian. Restricted late Oligocene, bimodal, transitional to alkaline magmatism located in the eastern sector of Aysén has been interpreted as formed in an incipient rift setting (e.g., Morata et al., 2003).

Low-grade metasedimentary rocks of the study area
Between 43° and 46° S the late Oligocene to early Miocene record mostly consists of marine sedimentary and volcano-sedimentary rock units. Near La Junta, sedimentary rocks of the La Junta and Vargas formations crop out along the eastern and western sides of the LOFZ, respectively .
The La Junta Formation (Urbina, 2001), firstly named as "Estratos de la Junta" by Bobenrieth et al. (1983), comprises tilted successions of mainly coarse-grained sedimentary rocks ( Fig. 3A) interbedded with minor andesites, cropping out in fault contact with Jurassic volcanic rocks or resting unconformably over the Lower to Upper Cretaceous pink granites of the North Patagonian Batholith. The clastic components have been interpreted as fluvial to alluvial fan deposits . They include ortho-and paraconglomerates together with coarse-grained sandstones. Porphyritic andesite and rhyodacite together with coarse-grained pink granite are among the lithologies described by Urbina (2001) for the conglomerate boulders. Very low-grade metamorphic minerals (chloriteepidote-pumpellyite-prehnite) occur in vesicles or as massive granular aggregates (Urbina, 2001). Encinas et al. (2014) have reported a ca. 26 Ma (late Oligocene) maximum sedimentation age for a >1 m thick volcanic sandstone belonging to the La Junta Formation; prominent Cretaceous populations are also observed in the detrital zircon age spectra (ca. 97-108 Ma).
The marine strata of the Vargas Formation are characterized by successions of fossiliferous black shale and mudstone interbedded with finegrained sandstone and siltstone, which are found in tectonic contact with cataclastic plutonic rocks of the North Patagonian Batholith (Urbina, 2001). Conspicuous foliation led Steffen (1944) to name this unit "Formación Esquistos Arcillosos". Bobenrieth et al. (1983) included these rocks as part of "Estratos de la Junta", but they did not recognize a marine origin for them. Encinas et al. (2014) reported U-Pb LA-ICP-MS detrital zircon ages for two samples which yield prominent Cretaceous (ca. 82-109 Ma) peaks, one of them also displaying a minor (n=4) late Eocene (ca. 39 Ma) age.
Marine volcano-sedimentary rocks of the Traiguén Formation are found in the southern section of the study area, on Isla Magdalena and nearby inland areas (Espinoza and Fuenzalida, 1971;Fuenzalida and Etchart, 1975;Bobenrieth et al., 1983;Hervé et al., 1994). This formation consists of pillow basalts with mixed within-plate/volcanic-arc geochemical signatures (Hervé et al., 1995) and turbiditic sedimentary packages deposited at bathyal depths (>1,000 m) (Encinas et al., 2016a and references therein). As reported by Hervé et al. (1994), the basal contact is represented by conglomerates and breccias, with clasts of metamorphic, granitic and acid volcanic rocks, resting unconformably over the Main Range Metamorphic Complex. The same authors describe N10E-trending open folds with subvertical axial planes affecting the Traiguén Formation, with local development of axial plane cleavage in the shales. A similar strike is observed for the partly syn-sedimentary mafic dykes intruding the Traiguén Formation and metamorphic basement in the area. According to Hervé et al. (1994), the deepest part of the basin was located to the east of Isla Magdalena, next to the main trace of the LOFZ: the basin was shallower to the west, where basaltic pillow lavas are absent and acid lava flows, porphyries and breccias have been described (Hervé et al., , 1995Bobenrieth et al., 1983).
The age of deposition of this formation is constrained by a ca. 26 Ma maximum sedimentation age determined at its type locality on Isla Traiguén , and by a U-Pb zircon age of ca. 23 Ma for a lapilli tuff in the same area (Encinas et al., 2016a). Hervé et al. (1995) obtained two imprecise Rb-Sr ages of 20±28 Ma and 20±26 Ma from sedimentary and volcanic rocks on Isla Magdalena, interpreted as related to their metamorphism. A minimum age is given by a ca. 20 Ma cross-cutting intrusion in the NE part of Isla Magdalena (Rb-Sr isochron by Pankhurst et al., 1999). A notably younger mid-Miocene (ca. 10 Ma) peraluminous igneous intrusion is recognized adjacent to the LOFZ in the lower course of Río Cisnes (Mella and Duhart, 2011). It is a partly foliated leucocratic granitoid containing spessartine-rich garnet, white mica, andalusite and sillimanite as primary minerals (Hervé et al., 1993). At its eastern edge, the Río Cisnes leucogranite intrudes a sequence of pelitic hornfelses and metaconglomerates which were described by Bobenrieth et al. (1983) as metamorphosed equivalents of the Traiguén Formation.

Methodology and materials
Detrital zircon was separated from two samples of low-grade metasedimentary rocks from Puerto Cisnes-Queulat area and one paraconglomerate sample from the La Junta area by standard methods of crushing, grinding, Wilfley table, magnetic and heavy liquid separation at Universidad de Chile, Santiago. U-Pb analyses were undertaken at the Research School of Earth Sciences, The Australian National University, Canberra. The zircon grains were mounted in epoxy and polished to expose the interior. Cathodoluminescence (CL) images were obtained for all grains to select appropriate areas for analysis. U-Th-Pb analyses were carried out using sensitive high-resolution ion microprobes (SHRIMP II and SHRIMP RG) with procedures similar to those described by Williams (1998;and references therein). Sixty grains were analysed for sample FO1104 and twenty grains each for samples FO1101 and FO1105. Although 20 analyses do not give statistically complete provenance spectra, they can nevertheless help to restrict the maximum depositional age.
The analytical data were plotted on Tera-Wasserburg (1972) Concordia diagrams and the derived radiogenic ages were plotted on relative probability diagrams ( Fig. 4) using Isoplot (Ludwig, 2003). Maximum depositional ages may be assessed by different statistical methods (see Dickinson and Gehrels, 2009): in this work we used a conservative estimate based on the mean age of the youngest cluster consisting in all cases of more than three grains. Ages for individual grains are reported at the 68% confidence level (Table 1).
Structural analysis of the studied Cenozoic units is beyond the scope of the present paper, but general structural characterization is given when considered necessary to establish some similarities with other Cenozoic units of the area.

Results
Sample FO1101 (43°56'52.0" S/72°23'33.0" W) was collected 1 km north of the town of La Junta and belongs to the La Junta Formation (Fig.3A). The outcrop consists of a paraconglomerate with well-rounded andesitic and minor granitic clasts 10-20 cm in diameter and a coarse-grained matrix with 1-2 cm clasts. The rocks do not exhibit foliation, but are affected by very low-grade regional metamorphism. The sample was taken from the matrix and the results show a prominent age peak at 98 Ma but with five of the twenty zircon grains giving ages of 25-31 Ma: three of these yield a consistent weighted mean age of 28±1 Ma (Fig. 4).
Sample FO1104 (44°38'21.3" S/72°26'23.4" W) is a foliated metaconglomerate from Queulat area with flattened clasts 1 to 5 cm long immersed in a greenish matrix (Fig. 3C). The metaconglomerate occurs within a thick pile of alternating packages of green phyllite and metasandstone, resembling turbidite deposits ( Fig 3B, D). The So is NNE/40WNW. They contain isoclinally folded calcite (Fig. 3E) veins together with a N80W/20N main axial plane foliation (Sp). Structures developed on the foliation plane indicate dextral shear (Fig 3F). Nearly vertical, green microdiorite post-tectonic dykes a few metres wide, some with slightly sinuous margins, cross-cut the low-grade metamorphic rocks (Fig. 3B). The more complete detrital zircon spectrum for this sample exhibits a prominent age peak at 35 Ma (n=10), clearly indicating a mid-Cenozoic maximum depositional age. However, ages tail down to a minimum of ca. 23 Ma, with two possible minor age peaks at 26 Ma (n=3) and 29 Ma (n=4). In addition, there are older age peaks at 39 and 96 Ma (Fig. 4).
Sample FO1105 (44°45'33.3" S/72°38'50.9" W) is a schist from a cutting in the Puerto Cisnes-Queulat road. It is well foliated and banded, with post-tectonic randomly-orientated biotite microporphyroblasts in a quartz-rich matrix. The Sp N50E/58NW fabric is a crenulation cleavage. The detrital zircon ages (Fig. 4) show evidence for both Permian (ca. 290 Ma) and Cretaceous (ca. 130 Ma) provenance, but 16 of the 20 grains gave Paleogene ages of 26-39 Ma, half of these being Oligocene. A conservative estimate of the maximum sedimentation age is 28±1 Ma, given by the youngest 6 ages, albeit with some scatter beyond the analytical uncertainty. The well-defined peak at ca. 39 Ma (n=6) also appears to represent a significant provenance age (Fig. 4).

Age of the sedimentary protolith and stratigraphic correlations with geological units of the North Patagonian Andes
The ca. 28 Ma age obtained here for detrital zircon in the two metamorphic rocks from the Puerto Cisnes-Queulat area (Fig. 4), implies probable late Oligocene (Rupelian-Chattian) deposition. It precludes previous correlation with the Paleozoic Main Range Metamorphic Complex (e.g., SER NAGEOMI N, 2003), but validates the correlation of these rocks with the Traiguén Formation Encinas et al., 2016a), as previously suggested by Bobenrieth et al. (1983). Therefore, these rocks constitute the easternmost known outcrops of the Traiguén Formation.
In the North Patagonian Andes of Chile at 42°-46° S, most of the late Oligocene-early Miocene marine strata (Ayacara, Puduhuapi, Vargas and Traiguén formations) are located to the west of a N-S trending belt of (mostly) Lower to Upper Cretaceous plutonic rocks belonging to the North Patagonian Batholith (Pankhurst et al., 1992;Pankhurst et al., 1999;Duhart, 2008) (Fig. 1). These volcanosedimentary units share sedimentological features indicative of outer-shelf to deep-sea deposition in basins located adjacent to coeval volcanic edifices (e.g., Levi et al., 1966;Encinas et al., 2013). On the other hand, restricted outcrops of late Oligocene-early Miocene strata deposited in a shallow-marine environment are located in the eastern reaches of the batholith (e.g., La Cascada Formation, Thiele et al., 1978) or tens of km farther east (e.g., Guadal Formation). Based on paleontological constraints, an Atlantic affinity is well-documented for the Guadal Formation (Frassinetti and Covacevich, 1999; among others), contrasting with the Pacific affinity of the marine units to the west. The affinity of sedimentary rocks of the La Cascada Formation is more debatable , as its position east of the Cretaceous batholith and shallow sedimentary environment show marked differences with the above mentioned marine formations located near to or west of the LOFZ.
The only known non-marine strata in the western Andean slope are the coarse-grained (alluvial?) sedimentary rocks of the La Junta Formation. According to Bobenrieth et al. (1983), in the Queulat area there is a package of coarse-grained conglomerate with 5-10 cm clasts of dacitic, andesitic and granitic composition disposed in a tuffaceous matrix intensely deformed by dynamic metamorphism. These authors correlated this with the La Junta Formation, whose type locality is 70 km further north. When the detrital zircon age spectra of the Queulat metaconglomerate (sample FO1104) is compared with that of the La Junta coarse-grained paraconglomerate (sample FO1101), similar maximum possible sedimentation ages are obtained as well as the same major Cenomanian age provenance (96-99 Ma). These results are in agreement with those obtained by Encinas et al. (2014) for the same unit (sample JUN-1, Table 2), suggesting that they are coetaneous and that the La Junta Formation may be a high-energy lateral facies variant of the Traiguén Formation.
At Caleta Ayacara (Fig. 1), the base of the exposed lower member of the Ayacara Formation (Levi et al., 1966) consists of mostly massive (ortho-and para-) conglomerates, tens of metres thick with subangular to rounded clasts whose size varies from millimetres to several tens of centimetres. Aphanitic and trachytic andesite, tuff and minor dacite are the most common lithology for the clasts, as well as plutonic rocks here (Encinas et al., 2013). These  characteristics resemble those of the La Junta Formation (Urbina, 2001). According to Encinas et al. (2014), the La Junta Formation may have been deposited during the initial stages of subsidence that rapidly led to marine ingression and deposition of the siltstone, fossiliferous black shale and fine-grained sandstone of the Vargas Formation (Urbina, 2001). These marine strata are highly deformed and foliated, and sedimentary structures are not preserved. Nevertheless, their lithological association, with a high content of organic matter as indicated by their black color, the occurrence of poorly preserved gastropods, bivalves, echinoderms and planktonic foraminifera, plus the common occurrence of pyrite, are all features that resemble those exhibited by the "Siltstone and Very Fine-Grained Sandstone" sedimentary facies defined by Encinas et al. (2013) for a portion of the upper member of the Ayacara Formation.
Despite the limited number of analyses comprising the age spectra reported here, there is a marked difference between the sedimentary rocks of the Traiguén Formation provenance in the Puerto Cisnes-Queulat area and the results obtained by  and Encinas et al. (2016a) around its type locality (Table 2). In our study area, there is a relative absence of detrital zircon older than Late Cretaceous (except for a small number of Early Cretaceous and Permian ages), whereas the Traiguén Formation to the south shows a marked presence of Early Cretaceous and older reworked zircon derived from the metamorphic complexes, with source areas to the west and east as suggested by Encinas et al. (2016a). At the latitude of Queulat it seems that Cenomanian zircons represent the only significant pre-Cenozoic zircon population, presumably derived from plutonic rocks of this age in the North Patagonian Batholith immediately to the east (Pankhurst et al., 1999;Urbina, 2001;De la Cruz and Cortés, 2011). Similar detrital zircon age peaks are recognized in the La Junta and Vargas formations (this work; Encinas et al., 2014), and in the lower member of the Ayacara Formation (Encinas et al., 2013) (Table 2),

Age constraints on the metamorphism of the Traiguén Formation in the Puerto Cisnes-Queulat area
Even though no radiometric ages are reported here for the metamorphism of the studied rocks, some limits may be inferred if we take into account its relationship suggesting the existence of an emerged ridge of plutonic rocks marking the eastern border of the marine basins. Colwyn et al. (2019) also postulate the existence of a topographic barrier similar to the modern mountain range, to explain a rain shadow in extra-Andean Patagonia indicated by δD isotope data, at least since Paleocene times.   to Neogene magmatism in the area (Fig. 2). Plutonic rocks in the Queulat-Puerto Cisnes-Isla Magdalena area have been dated by various geochronological methods (Hervé et al., 1993;Pankhurst et al., 1999;Parada et al., 2000;Cembrano et al., 2002;Mella and Duhart, 2011), yielding results between 10 and 20 Ma. The most voluminous intrusive rocks in the Queulat area correspond to the dioritic and tonalitic facies of the Queulat Diorites (informal name) of Parada et al. (2000), who report that they intrude "highly deformed metapelites of unknown age". The latter rocks are here confirmed as belonging to the Traiguén Formation. 40 Ar/ 39 Ar ages of 16-18 Ma in amphibole of the Queulat Diorites are consistent with the ca. 15 Ma Rb-Sr whole-rock isochron obtained by Pankhurst et al. (1999) in granodiorite and tonalite at Seno Ventisquero (north of Queulat, Fig. 2), and with the ca. 14.5 Ma hornblende and biotite 40 Ar/ 39 Ar ages obtained by Cembrano et al. (2002) for a non-deformed diorite sampled in the same area. There is also a 15.2±0.19 Ma SHRIMP U-Pb crystallization age for the Cerro Esternón amphibole±biotite tonalite (Fig. 2), a stock located just south of Puerto Cisnes (Mella and Duhart, 2011).
To the west, at Isla Magdalena, Pankhurst et al. (1999) obtained consistent ca. 20 Ma Rb-Sr wholerock isochrons for biotite granodiorite intruding the Traiguén Formation. These geochronological data attest to a relatively significant episode of magma emplacement during 20-10 Ma, particularly between 20-15 Ma. Plutonic rocks from this episode intrude the Main Range Metamorphic Complex, as well as the Cretaceous rocks of the batholith and the metasedimentary rocks of the Traiguén Formation and suggest a minimum age for the regional metamorphism affecting the latter. Randomly orientated biotite micro-porphyroblasts in the Puerto Cisnes schist were generated by contact metamorphism and postdate the banding and crenulation cleavage formed during regional metamorphism. Parada et al. (2000) describe the garnet-biotite-staurolite-andalusite-sillimanite mineral paragenesis in nearby pelitic hornfels, deducing a 3 kbar maximum pressure for the contact metamorphism. Hervé et al. (1993) reported a similar pressure of emplacement for the Rio Cisnes leucogranite stock, which intruded the metamorphic rocks of the Traiguén Formation at 10 Ma (Mella and Duhart, 2011). This relationship implies that the Traiguén Formation was already folded and metamorphosed before intrusion of the Río Cisnes stock and generation of the contact metamorphic aureole.
At the north-eastern tip of Isla Refugio (Fig. 2), ca. 60 km west of La Junta (43°50' S), Bobenrieth et al. (1983) assigned a package of volcanic rocks to the Traiguén Formation, some of them with preserved pillow structures (Fig. 3H). These rocks grade into mylonitic schists in a 2 km long west-toeast transect. The main foliation is approximately NNE and dips 70°-80° E, with a dextral sense of shear (Fig. 3G), resembling the modern kinematics of the LOFZ. Post-tectonic microdiorite and aplite dykes were emplaced parallel to the main foliation. Thus, the timing of deformation should be older than 15.4±0.5 Ma, the whole-rock/biotite Rb-Sr isochron age obtained by Pankhurst et al. (1999) in a non-deformed suite of granodiorites, microdiorite and aplite mapped as intruding the rocks of the Traiguén Formation on the same island (Fig. 2). Late Miocene LOFZ-related mylonites have been recognized in the study area (e.g., Cembrano et al., 2002), and a previous early-to-mid Miocene event of deformation and metamorphism is recorded by the data presented here.
The Cenozoic growth of the North Patagonian Andes between 45° S and 47° S has been recently addressed by Folguera et al. (2018a). During this Era, they identified a discrete pulse of contraction at ca. 16-18 Ma on the basis of U-Pb detrital zircon ages from synorogenic strata located to the east of the Cretaceous outcrops of the North Patagonian Batholith. To the east of Queulat, in the Alto Río Cisnes area, a tuff interleaved with fluvial syntectonic strata of the Río Frías Formation has yielded a 15.8 Ma U-Pb zircon age (Encinas et al., 2016b), confirming the early-mid Miocene lateral expansion of the Patagonian Andes at these latitudes. These ages are similar to the above-mentioned ca. 15-20 Ma crystallization ages for the batholith in the Queulat area, and are in agreement with the beginning of transpression along the LOFZ at ca. 16 Ma deduced from fission track ages (Thomson, 2002). Parada et al. (2000) suggest that the diorites and tonalites of the Queulat area were produced by melting of the lower crust at ca. 33 km depth. Such deep partial melting was ascribed to high exhumation rates (between 1-2 mm/yr) due to vertical movement along the LOFZ. Hervé et al. (1993) explained the formation of the Río Cisnes leucogranite in a similar way. In this scenario, tectonic inversion of the Traiguén Basin in the Queulat area would have occurred during early to middle Miocene times, roughly coeval with the early development of the continental foreland system to the east and major batholith emplacement in the Main Cordillera.
During these processes, tectonic emplacement and metamorphism of ultramafic bodies occurred around the Llancahué-Ayacara area (Hervé et al., 2017;González, 2018) and also to the south, in Isla Traiguén and Isla Magdalena, as shown by N-S trending positive gravity gradient anomalies (Folguera et al., 2018b). These ultramafic bodies may be a proxy for the amount of extension generated during opening of these basin and the depth of the detachment fault during their closure.

Paleogene magmatism along the LOFZ?
The U-Pb detrital zircon ages reported in this contribution together with previously published data for the late Oligocene to early Miocene marine sedimentary rocks (Table 2), allows a N-S comparison of the basins located close to the LOFZ between 42° S and 46° S Encinas et al., 2013;Encinas et al., 2014;Encinas et al., 2016a;Hervé et al., 2017). Sediment provenance here is important as an indirect evidence of magmatic evolution, since the outcrop record is limited due to large-scale denudation during late Cenozoic times (Thomson, 2002;Adriasola et al., 2005) and the dense vegetation cover of the area. The distribution of detrital zircon ages shows main relative probability peaks of early Miocene (ca. 23-17 Ma), late Oligocene (ca. 28-25 Ma), late Eocene-early Oligocene (ca. 39-32 Ma) and early Eocene (ca. 53-50 Ma). Although the early Neogene peaks might correspond to now-eroded early Miocene extrusive equivalents of the North Patagonian Batholith, the source of the Paleogene detrital zircons is less obvious. Paleogene magmatic rocks are found hundreds of km to the east in the Pilcaniyeu and El Maitén volcanic belts along the western edge of the North Patagonian Massif (e.g., Rapela et al., 1988;Iannelli et al., 2017; and, more restrictedly, tens of km east in the Alto Rio Císnes area (Prieto and Cortés, 1995;De la Cruz and Cortés, 2011) and the Meseta Guadal area . These are potential sources for the Paleogene detrital zircons, however, the likely existence of an emerged ridge to the east of the basins, the immature nature of some of the protoliths and sedimentary rocks (e.g., the Queulat metaconglomerate and the La Junta Formation) and the occurrence of scattered Paleogene magmatic rocks along the LOFZ, all favour the possibility of a more local derivation, as discussed below.
Basaltic pillow lavas have been the most studied components of the Traiguén Formation volcanism, but this unit also includes intermediate to felsic igneous rocks. Bobenrieth et al. (1983) and Hervé et al. (1994Hervé et al. ( , 1995 refer to the existence of felsic tuffs, dacite lava flows and porphyritic dacites and rhyolites, particularly on Isla Magdalena. Bobenrieth et al. (1983) and Urbina (2001)  Late Eocene-early Oligocene (39-32 Ma) detrital zircons are abundant in the rocks sampled, as well as in those studied by Hervé et al. (2017) on Isla Llancahué, where they reported a late Eocene maximum possible sedimentation age for a foliated metasandstone with graded bedding, interleaved with black slate showing slump structures. At Llancahué, the metasedimentary rocks are related to and (most probably overlie) pillow metabasalts with a common foliation (Hervé et al., 2017)-a lithological association that resembles that of the Traiguén Formation. This age compares with that of early Oligocene volcanism recognized on Isla Mitahués (Encinas et al., 2016a) and with the K-Ar age peak population of ca. 34 Ma reported by Herrera (2000) for the dyke swarm intruding the rocks of the Traiguén Formation. In addition, late Eocene plutonic rocks are also spatially related to both the Traiguén Formation and the LOFZ in the archipelagos of Aysén (Pankhurst et al., 1999).
Paleocene to early Eocene detrital zircons ages have not been found in the study area and their occurrence is restricted to the Llancahué epimetamorphic complex, from a metamorphosed tuff interleaved with micaschist, metasandstones and minor metabasites (Hervé et al., 2017). The only known plutonic rocks of similar age in the area are located close to the LOFZ around Lago Yelcho (ca. 43°20' S) and have K-Ar ages of 50-55 Ma (Duhart, 2008).
Thus, sporadically, and spatially distributed Paleogene magmatism was focalized along structures corresponding to the modern LOFZ, suggesting a zone of crustal weakness prior to Neogene times (similarly to the Proto Liquiñe-Ofqui fault of Aragón et al., 2011). Hervé (1976) was the first to propose ancient displacements along the LOFZ based on the existence of undeformed dykes crosscutting mylonites near Liquiñe (ca. 39° S) and interpreted the former as Late Cretaceous to early Cenozoic in age by correlation with dated intrusive rocks cropping out in the area. Later studies dated various lithologies of hypabyssal intrusives with similar crosscutting relationships elsewhere in the Liquiñe area, obtaining pre-Neogene ages of 29 Ma (whole rock K-Ar by Hervé et al., 1979), 48 Ma ( 40 Ar/ 39 Ar biotite stepheating by Schermer et al., 1996) and 100 Ma ( 40 Ar/ 39 Ar amphibole step-heating by Cembrano et al., 2000). In accordance with this, Bourguois et al. (2016) infer that the inception of the Golfo de Penas basin, whose evolution is controlled by the LOFZ, is represented by the deposition of the marine beds of the mid-Eocene Puerto Good Sequence (Forsythe et al., 1985).

Tectonic context
The new data and synthesis presented in this work argue in favour of the LOFZ exerting structural control on Cenozoic magma emplacement and basin formation. The fault system would have been reactivated with kinematics appropriate to the prevailing subduction parameters (e.g., Cembrano et al., 2000). In Paleogene times the low obliquity and slow subduction of the Farallon plate would have promoted margin-parallel transtensional tectonics (Hervé et al., 1995;Aragón et al., 2011) leading to the formation of a chain of small volcano-sedimentary basins during the northward drift of the peninsular coastal block (or the Chiloé block in Fig. 5), in accordance with the buttressing model of Beck et al. (1993). On the other hand, the faster and nearly orthogonal late Oligocene to early Miocene subduction of the Nazca plate (Fig. 5) led to vigorous slab roll-back (e.g., Muñoz et al., 2000;Fennell et al., 2018), enhanced stretching in FIG. 5. Schematic E-W geological cross-section through the Queulat area showing paleogeographic reconstruction during Oligocene to early Miocene times based on data and interpretations summarized in the text. AFT: Apatite fission tracks ages after Thomson et al. (2001). Oceanic-like mafic crust was emplaced in zones of maximum extension. Basin depth variations after Hervé et al. (1994). NPB: North Patagonian Batholith.
the upper plate and widespread magmatism in the forearc to the backarc (Muñoz et al., 2000;Encinas et al., 2016a;Ianelli et al., 2017;Fernandez Paz et al., 2019 and references therein). The climax of the extension is recorded in the southern sectors of the LOFZ, at these latitudes it is thought that the Chiloé block was detached from the continent during the retreat of the trench towards the ocean, then colliding against the stable continent during the middle Miocene (Hervé et al., 2017).

Conclusion
The ca. 28 Ma youngest detrital zircons ages obtained from the low-grade metamorphic rocks of Puerto Cisnes-Queulat area clearly indicate that the protoliths were deposited during Rupelian-Chattian, precluding correlation with the Paleozoic rocks of the Main Range metamorphic complex to the west, but validating correlation with the metasedimentary rocks of the Traiguén Formation, as previously suggested by Bobenrieth et al. (1983). Similar detrital zircon age patterns in rock samples from the La Junta and Traiguén formations suggest that the former represents a high energy lateral facies change of the latter, deposited in a basin -or basins-bounded to the east by an emerged ridge of Cretaceous plutonic rocks (Fig. 5).
The wide areal distribution of metamorphic rocks with protoliths of early-to-mid Cenozoic age in a similar position with respect to the main lineament of the LOFZ (Hervé et al., 2017) suggests a regional pattern of early Neogene deformation and metamorphism associated with the closure of the intra-arc basin, or basins, located in the western slope of the North Patagonian Andes.
Even though marine ingressions covered wide areas of southern South America during late Oligoceneearly Miocene times as result of regional extension (see Encinas et al., 2018 for review), deep-marine sedimentation together with the generation of quasioceanic crust is restricted to the LOFZ domain (Hervé et al., 1995;Silva et al., 2003;Hervé et al., 2017). Although more studies should be carried out to understand the associated mechanisms in detail, the crustal scale discontinuity represented by the LOFZ appears to have played an important role during early-to-mid Cenozoic magmatic activity, and the opening and subsequent closure of basins in the western slope of North Patagonian Andes.